Anthropogenic nutrient input has caused a rapid expansion of bottom water hypoxia in the Baltic Sea over the past century. Two earlier intervals of widespread hypoxia, coinciding with the Holocene Thermal Maximum (HTMHI; 8-4 ka before present; BP) and the Medieval Climate Anomaly (MCA(HI); similar to 1200-750 years BP), have been identified from Baltic Sea sediments. Here we present sediment records from two sites in the Baltic Sea, and compare the trace metal (As, Ba, Cd, Cu, Mo, Ni, Pb, Re, Sb, Tl, U, V, Zn) enrichments during all three hypoxic intervals. Distinct differences are observed between the intervals and the various elements, highlighting the much stronger perturbation of trace metal cycles during the modern hypoxic interval. Both Mo and U show a strong correlation with C-org and very high absolute concentrations, indicative of frequently euxinic bottom waters during hypoxic intervals. During the modern hypoxic interval (Modern(HI)) comparatively less Mo is sequestered relative to C-org than in earlier intervals. This suggests partial drawdown of the water column Mo inventory in the modern water column due to persistent euxinia and only partial replenishment of Mo through North Sea inflows. Molybdenum contents in modern sediments are likely also affected by the recent slowdown in input of Mo in association with deposition of Fe and Mn oxides. Strong enrichments of U in recent sediments confirm that the Modern(HI) is more intense than past intervals. These results suggest that U is a more reliable indicator for the intensity of bottom water deoxygenation in the Baltic Sea than Mo. Sedimentary Re enrichment commences under mildly reducing conditions, but this element is not further enriched under more reducing conditions. Enrichments of V are relatively minor for the MCA(HI) and Modern(HI), possibly due to strong reservoir effects on V in the water column, indicating that V is unreliable as an indicator for the intensity of bottom water hypoxia in this setting. Furthermore, Ba profiles are strongly influenced by post-depositional remobilization throughout the Holocene. The strong relationship between C-org and Ni, Tl and particularly Cu suggests that these trace metals can be used to reconstruct the C-org flux into the sediments. Profiles of As, Sb and Cd and especially Pb and Zn are strongly influenced by anthropogenic pollution.

Diagnostic mirrors are planned to be used in all optical diagnostics in ITER. Degradation of mirrors due to e.g. deposition of plasma impurities will hamper the entire performance of affected diagnostics. in situ mirror cleaning by plasma sputtering is presently envisaged for the recovery of contaminated mirrors. There are observations showing a signature of sputtering dependence on crystal orientation. Should such a dependence exist, the sputtering of single crystal mirrors could be minimized, thus prolonging a mirror lifetime. Four single crystal molybdenum mirrors with different orientations were produced to study the effect of crystal orientation on sputtering. Mirrors were exposed to argon plasma under identical plasma conditions relevant to those expected in the mirror cleaning systems of ITER. The energy of impinging ions was about 60 eV. The amount of sputtered material corresponded to about a hundred mirror cleaning cycles in argon. Plasma exposures did not affect the mirror reflectivity. The maximum decrease of specular reflectivity did not exceed 5% at 250 nm. The mirrors with orientations [110]/[101] demonstrated up to 42% less sputtering than the mirrors with other crystal orientations. These findings outline the advantage of a favorable crystal orientation for a cleaning of heavy contaminants from ITER mirrors.