Browsing by Subject "NANOSPHERES"

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  • Keinanen, Outi; Dayts, Eric J.; Rodriguez, Cindy; Sarrett, Samantha M.; Brennan, James M.; Sarparanta, Mirkka; Zeglis, Brian M (2021)
    The proliferation of plastics in the environment continues at an alarming rate. Plastic particles have been found to be persistent and ubiquitous pollutants in a variety of environments, including sea water, fresh water, soil, and air. In light of this phenomenon, the scientific and medical communities have become increasingly wary of the dangers posed to human health by chronic exposure to microplastics (
  • Agustin, Melissa; Penttilä, Paavo; Lahtinen, Maarit; Mikkonen, Kirsi S. (2019)
    The production of lignin nanoparticles (LNPs) has opened new routes to the utilization of lignin in advanced applications. The existing challenge, however, is to develop a production method that can easily be adapted on an industrial scale. In this study, we demonstrated a green and rapid method of preparing LNPs directly from a sulfur-free alkaline pulping liquor by combining acid precipitation and ultrasonication. The combined method produced spherical LNPs, with a hierarchical nanostructure and a highly negative surface charge, within only 5 min of sonication. The mild, rapid sonication was achieved by sonicating directly without prior drying of the acid-precipitated and dialyzed lignin. Optimization of the method revealed the potential for minimizing acid consumption, shortening the dialysis time, and processing directly the alkaline liquor with as much as 20 wt % lignin. The isolated LNPs were stable during storage for 180 days, at a pH range of 4–7, and in a dispersing medium below 0.1 M NaCl. The LNPs also displayed excellent emulsifying properties, stabilizing oil-in-water emulsions. Thus, this simple and energy-efficient method opens a sustainable, straightforward, and scalable route to the production of organic solvent-free LNPs, with high potential as interface stabilizers of multiphase systems in the food and medical industries.