Browsing by Subject "Volatiles"

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  • Tuccillo, Fabio (Helsingin yliopisto, 2021)
    As the number of vegetarians and flexitarians is increasing, the demand for meat alternatives is following the same trend. Faba bean is a promising crop for environmental, health, and social reasons. From its seeds, several products can be produced, such as flour, protein concentrate, and protein isolate. These materials can be further processed for the development of texturized vegetable proteins. In this context, high moisture extrusion (HME) is an innovative technology, which requires more water, but milder temperatures than the more studied low moisture extrusion. The present thesis aimed at covering the current knowledge gap on this technology, by focusing on the flavor aspect of faba bean-based meat alternatives. The volatile profile of faba bean flour, protein concentrate, protein isolate, and mixtures was studied before and after high moisture extrusion by means of HS-SPME-GC-MS. Comparisons were made between raw materials (flour, protein concentrate, protein isolate, mixtures) and extrudates. The effect of the origin (Canadian and Finnish) of the protein concentrate was also investigated. Materials were also characterized for the following aspects: moisture, ash, protein, lipids, lipid-degrading enzymes (lipase and lipoxygenase), free amino acids, and free mono-, di-, and oligosaccharides. Several classes of volatile compounds were observed in both raw materials and extrudates, namely organic acids, alcohols, aldehydes, alkanes, alkenes, aromatic compounds, furans, esters, ketones, nitro compounds, and terpenes. Many compounds were characteristic of only one material, demonstrating that the formation of certain volatiles was product dependent. However, some other compounds were found in all materials, such as 1-hexanol, hexanal, and 2-pentylfuran. Literature addresses these compounds as responsible for the beany flavor. HME caused the inactivation of lipase and lipoxygenase but did not prevent the formation of lipid oxidation products. Products from Maillard reaction were not found in the extrudates. After HME, 1-hexanol levels decreased, whereas the abundance of 2-pentylfuran significantly increased. The behavior of hexanal after HME was less stable and predictable than the two beforementioned compounds. Not only these novel findings could have application in product development, but they also laid the basis for further research aimed at improving the flavor of faba bean.
  • Rothery, David A.; Massironi, Matteo; Alemanno, Giulia; Barraud, Oceane; Besse, Sebastien; Bott, Nicolas; Brunetto, Rosario; Bunce, Emma; Byrne, Paul; Capaccioni, Fabrizio; Capria, Maria Teresa; Carli, Cristian; Charlier, Bernard; Cornet, Thomas; Cremonese, Gabriele; D'Amore, Mario; De Sanctis, M. Cristina; Doressoundiram, Alain; Ferranti, Luigi; Filacchione, Gianrico; Galluzzi, Valentina; Giacomini, Lorenza; Grande, Manuel; Guzzetta, Laura G.; Helbert, Joern; Heyner, Daniel; Hiesinger, Harald; Hussmann, Hauke; Hyodo, Ryuku; Kohout, Tomas; Kozyrev, Alexander; Litvak, Maxim; Lucchetti, Alice; Malakhov, Alexey; Malliband, Christopher; Mancinelli, Paolo; Martikainen, Julia; Martindale, Adrian; Maturilli, Alessandro; Milillo, Anna; Mitrofanov, Igor; Mokrousov, Maxim; Morlok, Andreas; Muinonen, Karri; Namur, Olivier; Owens, Alan; Nittler, Larry R.; Oliveira, Joana S.; Palumbo, Pasquale; Pajola, Maurizio; Pegg, David L.; Penttilä, Antti; Politi, Romolo; Quarati, Francesco; Re, Cristina; Sanin, Anton; Schulz, Rita; Stangarone, Claudia; Stojic, Aleksandra; Tretiyakov, Vladislav; Vaisanen, Timo; Varatharajan, Indhu; Weber, Iris; Wright, Jack; Wurz, Peter; Zambon, Francesca (2020)
    BepiColombo has a larger and in many ways more capable suite of instruments relevant for determination of the topographic, physical, chemical and mineralogical properties of Mercury's surface than the suite carried by NASA's MESSENGER spacecraft. Moreover, BepiColombo's data rate is substantially higher. This equips it to confirm, elaborate upon, and go beyond many of MESSENGER's remarkable achievements. Furthermore, the geometry of BepiColombo's orbital science campaign, beginning in 2026, will enable it to make uniformly resolved observations of both northern and southern hemispheres. This will offer more detailed and complete imaging and topographic mapping, element mapping with better sensitivity and improved spatial resolution, and totally new mineralogical mapping. We discuss MESSENGER data in the context of preparing for BepiColombo, and describe the contributions that we expect BepiColombo to make towards increased knowledge and understanding of Mercury's surface and its composition. Much current work, including analysis of analogue materials, is directed towards better preparing ourselves to understand what BepiColombo might reveal. Some of MESSENGER's more remarkable observations were obtained under unique or extreme conditions. BepiColombo should be able to confirm the validity of these observations and reveal the extent to which they are representative of the planet as a whole. It will also make new observations to clarify geological processes governing and reflecting crustal origin and evolution. We anticipate that the insights gained into Mercury's geological history and its current space weathering environment will enable us to better understand the relationships of surface chemistry, morphologies and structures with the composition of crustal types, including the nature and mobility of volatile species. This will enable estimation of the composition of the mantle from which the crust was derived, and lead to tighter constraints on models for Mercury's origin including the nature and original heliocentric distance of the material from which it formed.