Origin of the high-temperature Olserum-Djupedal REE-phosphate mineralisation, SE Sweden : A unique contact metamorphic-hydrothermal system

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Andersson , S S , Wagner , T , Jonsson , E , Fusswinkel , T , Leijd , M & Berg , J T 2018 , ' Origin of the high-temperature Olserum-Djupedal REE-phosphate mineralisation, SE Sweden : A unique contact metamorphic-hydrothermal system ' , Ore Geology Reviews , vol. 101 , pp. 740–764 . https://doi.org/10.1016/j.oregeorev.2018.08.018

Title: Origin of the high-temperature Olserum-Djupedal REE-phosphate mineralisation, SE Sweden : A unique contact metamorphic-hydrothermal system
Author: Andersson, Stefan S.; Wagner, Thomas; Jonsson, Erik; Fusswinkel, Tobias; Leijd, Magnus; Berg, Johan T.
Contributor: University of Helsinki, Department of Geosciences and Geography
University of Helsinki, RWTH Aachen University
University of Helsinki, Department of Geosciences and Geography
Date: 2018-10
Language: eng
Number of pages: 25
Belongs to series: Ore Geology Reviews
ISSN: 0169-1368
URI: http://hdl.handle.net/10138/247108
Abstract: The Swedish part of the Fennoscandian Shield hosts a variety of rare earth element (REE) deposits, including magmatic to magmatic-hydrothermal types. This paper focuses on the origin of the Olserum-Djupedal REE-phosphate mineralisation located in the sparsely studied Västervik region, SE Sweden. Here, mineralisation occurs in three main areas, Olserum, Djupedal and Bersummen. Primary hydrothermal REE mineralisation formed at high temperatures (about 600°C), leading to precipitation of monazite-(Ce), xenotime-(Y), fluorapatite and minor (Y,REE,U,Fe)-(Nb,Ta)-oxides in veins and vein zones dominated by biotite, amphibole, magnetite and quartz. The veins are hosted primarily by metasedimentary rocks present close to, or within, the contact aureole of a local 1.8 Ga ferroan alkali feldspar granite pluton, but also occur within in the chemically most primitive granite in the outermost part of that pluton. In the Djupedal area, REE-mineralised metasedimentary bodies are extensively migmatised, with migmatisation post-dating the main stage of mineralisation. In the Olserum and Bersummen areas, the REE-bearing veins are cross-cut by abundant pegmatitic to granitic dykes. The field relationships demonstrate a protracted magmatic evolution of the granitic pluton and a clear spatial and temporal relationship of the REE mineralisation to the granite. The major and trace element chemistry of ore-associated biotite and magnetite support genetic links between all mineralised areas. Biotite mineral chemistry data further demonstrate a distinct chemical trend from metasediment-hosted ore-associated biotite distal to the major contact of the granite to the biotite in the granite-hosted veins. This trend is characterised by a systematic decrease in Mg and Na and a coupled increase in Fe and Ti with proximity to the granite-hosted veins. The halogen compositions of ore-associated biotite indicate elevated contents of HCl and HF in the primary REE mineralising fluid. Calculated log(fHF/fHCl) values in the Olserum area suggest a constant ratio of about -1 at temperatures of 650-550°C during the evolution of the primary hydrothermal system. In the Djupedal and Bersummen areas, the fluid locally equilibrated at lower log(fHF/fHCl) values down to -2. High Na contents in ore-associated biotite and amphibole, and the abundance of primary ore-associated biotite indicate a K- and Na-rich character of the primary REE mineralising fluid and suggest initial high-temperature K-Na metasomatism. With subsequent cooling of the system, the fluid evolved locally to more Ca-rich compositions as indicated by the presence of the Ca-rich minerals allanite-(Ce) and uvitic tourmaline and by the significant calcic alteration of monazite-(Ce). The later Ca-rich stages were probably coeval with low-temperature (200-500°C) Na-Ca metasomatism variably affecting the granite and the wall rocks, which in the latter case produced distinct white quartz-plagioclase rocks. All observations and data lead us to discard the prevailing model that the REE mineralisation in the Olserum-Djupedal district represents assimilated and remobilised former heavy mineral-rich beds. Instead, we propose that the primary REE mineralisation formed by granite-derived fluids enriched in REE and P that were expelled early during the evolution of a local granitic pluton. The REE mineralisation developed primarily in the contact aureole of this granite and represents the product of a high temperature contact metamorphic-hydrothermal mineralising system. The REE mineralisation probably formed synchronously with K-Na and subsequent Na-Ca metasomatism affecting the granite and the wall rocks. The later Na-Ca metasomatic stage is probably related to a regional Na ± Ca metasomatic and associated U ± REE mineralising system operating concurrently with granitic magmatism at c. 1.8 Ga in the Västervik region. This highlights the potential for discovering hitherto unknown REE deposits and for the reappraisal of already known deposits in this part of the Fennoscandian Shield.
Subject: Olserum
Djupedal
REE
Phosphate
Metasomatism
Halogen fugacity
SOUTHERN SWEDEN
GOLD
FLUID CHEMISTRY
ORE-DEPOSITS
U-PB
GRANITIC-ROCKS
CL-OH
RARE-EARTH-ELEMENT
KARR ALKALINE COMPLEX
GEOCHEMICAL CHARACTERISTICS
1171 Geosciences
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