Cesium and Strontium Contamination of Nuclear Plant Stainless Steel : Implications for Decommissioning and Waste Minimization

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http://hdl.handle.net/10138/305541

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Lang , A R , Engelberg , D L , Walther , C , Weiss , M , Bosco , H , Jenkins , A , Livens , F R & Law , G T W 2019 , ' Cesium and Strontium Contamination of Nuclear Plant Stainless Steel : Implications for Decommissioning and Waste Minimization ' , ACS Omega , vol. 4 , no. 11 , pp. 14420-14429 . https://doi.org/10.1021/acsomega.9b01311

Julkaisun nimi: Cesium and Strontium Contamination of Nuclear Plant Stainless Steel : Implications for Decommissioning and Waste Minimization
Tekijä: Lang, Adam R.; Engelberg, Dirk L.; Walther, Clemens; Weiss, Martin; Bosco, Hauke; Jenkins, Alex; Livens, Francis R.; Law, Gareth T. W.
Tekijän organisaatio: Department of Chemistry
Päiväys: 2019-09-10
Kieli: eng
Sivumäärä: 10
Kuuluu julkaisusarjaan: ACS Omega
ISSN: 2470-1343
DOI-tunniste: https://doi.org/10.1021/acsomega.9b01311
URI: http://hdl.handle.net/10138/305541
Tiivistelmä: Stainless steels can become contaminated with radionuclides at nuclear sites. Their disposal as radioactive waste would be costly. If the nature of steel contamination could be understood, effective decontamination strategies could be designed and implemented during nuclear site decommissioning in an effort to release the steels from regulatory control. Here, batch uptake experiments have been used to understand Sr and Cs (fission product radionuclides) uptake onto AISI Type 304 stainless steel under conditions representative of spent nuclear fuel storage (alkaline ponds) and PUREX nuclear fuel reprocessing (HNO3). Solution (ICP-MS) and surface measurements (GD-OES depth profiling, TOF-SIMS, and XPS) and kinetic modeling of Sr and Cs removal from solution were used to characterize their uptake onto the steel and define the chemical composition and structure of the passive layer formed on the steel surfaces. Under passivating conditions (when the steel was exposed to solutions representative of alkaline ponds and 3 and 6 M HNO3), Sr and Cs were maintained at the steel surface by sorption/selective incorporation into the Cr-rich passive film. In 12 M HNO3, corrosion and severe intergranular attack led to Sr diffusion into the passive layer and steel bulk. In HNO3, Sr and Cs accumulation was also commensurate with corrosion product (Fe and Cr) readsorption, and in the 12 M HNO3 system, XPS documented the presence of Sr and Cs chromates.
Avainsanat: ACCUMULATION
ADSORPTION
CORROSION BEHAVIOR
DECONTAMINATION
PRODUCTS
SORPTION
SPECTROSCOPY
SURFACES
TEMPERATURE
X-RAY PHOTOELECTRON
116 Chemical sciences
Vertaisarvioitu: Kyllä
Tekijänoikeustiedot: cc_by
Pääsyrajoitteet: openAccess
Rinnakkaistallennettu versio: publishedVersion


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