Synthesis and characterization of rigid [2.2]paracyclophane-porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes

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Knoll , D M , Wiesner , T B , Marschner , S M , Hassan , Z , Weis , P , Kappes , M , Nieger , M & Bräse , S 2019 , ' Synthesis and characterization of rigid [2.2]paracyclophane-porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes ' , RSC Advances , vol. 9 , no. 52 , pp. 30541-30544 . https://doi.org/10.1039/c9ra07055a

Title: Synthesis and characterization of rigid [2.2]paracyclophane-porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes
Author: Knoll, Daniel M.; Wiesner, Thomas B.; Marschner, Stefan M.; Hassan, Zahid; Weis, Patrick; Kappes, Manfred; Nieger, Martin; Bräse, Stefan
Other contributor: University of Helsinki, Department of Chemistry
Date: 2019-09-25
Language: eng
Number of pages: 4
Belongs to series: RSC Advances
ISSN: 2046-2069
DOI: https://doi.org/10.1039/c9ra07055a
URI: http://hdl.handle.net/10138/306278
Abstract: This work presents a new approach to prepare mono- and disubstituted linear rigid bimetallic [2.2]paracyclophane-porphyrin conjugates via palladium-mediated Stille cross-coupling reaction. The metalated porphyrin moiety can be varied allowing convenient access to modular metal-metal fixed-distance Cu/Zn complexes.
Subject: OPTICAL RESOLUTION
MACRO RINGS
PORPHYRINS
STRATEGY
114 Physical sciences
116 Chemical sciences
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