Centrifugal fractionation of softwood extracts improves the biorefinery workflow and yields functional emulsifiers

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http://hdl.handle.net/10138/306346

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Valoppi , F , Lahtinen , M , Bhattarai , M , Kirjoranta , S , Juntti , V , Peltonen , L , Kilpeläinen , P O & Mikkonen , K S 2019 , ' Centrifugal fractionation of softwood extracts improves the biorefinery workflow and yields functional emulsifiers ' , Green Chemistry , vol. 21 , no. 17 , pp. 4691-4705 . https://doi.org/10.1039/C9GC02007A

Title: Centrifugal fractionation of softwood extracts improves the biorefinery workflow and yields functional emulsifiers
Author: Valoppi, Fabio; Lahtinen, Maarit; Bhattarai, Mamata; Kirjoranta, Satu; Juntti, Venla; Peltonen, Leena; Kilpeläinen, Petri O.; Mikkonen, Kirsi S.
Other contributor: University of Helsinki, Helsinki Institute of Sustainability Science (HELSUS)
University of Helsinki, Department of Food and Nutrition
University of Helsinki, Department of Food and Nutrition
University of Helsinki, Department of Food and Nutrition
University of Helsinki, Drug Research Program
University of Helsinki, Department of Food and Nutrition





Date: 2019-09-07
Language: eng
Number of pages: 15
Belongs to series: Green Chemistry
ISSN: 1463-9262
DOI: https://doi.org/10.1039/C9GC02007A
URI: http://hdl.handle.net/10138/306346
Abstract: With the emerging bio-based technologies, the fractionation of complex biomass is essential to obtain value-added functional molecules for material, chemical, and energy production. The refining process of biomasses often requires the use of solvents and hazardous chemicals, whose removal after fractionation decreases the eco-compatibility of the process and increases the cost and time of the refinement. Softwood extracts obtained through the environmentally friendly pressurized hot water extraction are heterogeneous mixtures rich in hemicelluloses and lignin. Here we developed a simple, fast, organic solvent-free, and sustainable method to fractionate softwood extracts using centrifugal forces. The characteristics of each obtained fraction in terms of composition, macromolecular properties (particle size, molar mass, charge), interfacial activity, and stabilization capacity were highly dependent on the centrifugal force and time applied. The hemicellulose and lignin contents in the fractions were balanced by centrifugal forces to obtain functional emulsifiers that efficiently stabilized the oil/water interface. Through fractionation of softwood extracts, we also found that both the hemicelluloses and lignin particles are involved in emulsion interface formation and stabilization. Centrifugation is a scalable concept that can be feasibly and easily introduced into the biorefinery system and used to optimize the composition of biomass fractions for targeted purposes.
Subject: 116 Chemical sciences
SPRUCE GALACTOGLUCOMANNANS
LIGNIN
WOOD
STABILIZATION
OIL
EMULSIONS
HEMICELLULOSES
NANOFIBERS
PARTICLES
STABILITY
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