Bis-[3]Ferrocenophanes with Central >E-E'<Bonds (E, E'=P, SiH) : Preparation, Properties, and Thermal Activation

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Isenberg , S , Weller , S , Kargin , D , Valic , S , Schwederski , B , Kelemen , Z , Bruhn , C , Krekic , K , Maurer , M , Feil , C M , Nieger , M , Gudat , D , Nyulaszi , L & Pietschnig , R 2019 , ' Bis-[3]Ferrocenophanes with Central >E-E' <Bonds (E, E'=P, SiH) : Preparation, Properties, and Thermal Activation ' , Chemistryopen , vol. 8 , no. 10 , pp. 1235-1243 . https://doi.org/10.1002/open.201900182

Title: Bis-[3]Ferrocenophanes with Central >E-E'<Bonds (E, E'=P, SiH) : Preparation, Properties, and Thermal Activation
Author: Isenberg, Stefan; Weller, Stefan; Kargin, Denis; Valic, Srecko; Schwederski, Brigitte; Kelemen, Zsolt; Bruhn, Clemens; Krekic, Kristijan; Maurer, Martin; Feil, Christoph M.; Nieger, Martin; Gudat, Dietrich; Nyulaszi, Laszlo; Pietschnig, Rudolf
Other contributor: University of Helsinki, Department of Chemistry
Date: 2019-10
Language: eng
Number of pages: 9
Belongs to series: Chemistryopen
ISSN: 2191-1363
DOI: https://doi.org/10.1002/open.201900182
URI: http://hdl.handle.net/10138/306990
Abstract: Invited for this month's cover picture are the groups of Professors Rudolf Pietschnig at the University of Kassel, Professor Dietrich Gudat at the University of Stuttgart and Professor Laszlo Nyulaszi at the Budapest University of Technology and Economics. The cover picture shows the thermally induced homolytic cleavage of the central P-P bond in a phosphorus-rich bis-ferrocenophane furnishing P-centered radicals (as evidenced by the computed spin-density highlighted in blue). The central P-6 unit in the title compound is a structural analog of the connecting unit in Hittorf's violet phosphorus, which links the orthogonally arranged tubular entities. A portrait of the German physicist Johann Wilhelm Hittorf is included. Read the full text of their Full Paper at 10.1002/open.201900182.
Subject: phosphorus
ferrocene
homolytic bond cleavage
thermolysis
radicals
PERSISTENT PHOSPHINYL
X-RAY
MOLECULAR-STRUCTURE
CRYSTAL-STRUCTURE
PHOSPHORUS
RADICALS
ELECTROCHEMISTRY
DERIVATIVES
REDUCTION
ELEMENTS
116 Chemical sciences
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