Modeling deuterium chemistry in starless cores : full scrambling versus proton hop

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Sipilä , O , Caselli , P & Harju , J 2019 , ' Modeling deuterium chemistry in starless cores : full scrambling versus proton hop ' , Astronomy & Astrophysics , vol. 631 , A63 .

Title: Modeling deuterium chemistry in starless cores : full scrambling versus proton hop
Author: Sipilä, O.; Caselli, P.; Harju, J.
Contributor organization: Particle Physics and Astrophysics
Department of Physics
Date: 2019-10-22
Language: eng
Number of pages: 14
Belongs to series: Astronomy & Astrophysics
ISSN: 0004-6361
Abstract: We constructed two new models for deuterium and spin-state chemistry for the purpose of modeling the low-temperature environment prevailing in starless and pre-stellar cores. The fundamental difference between the two models is in the treatment of ion-molecule proton-donation reactions of the form XH+ + Y -> X + YH+, which are allowed to proceed either via full scrambling or via direct proton hop, that is, disregarding proton exchange. The choice of the reaction mechanism affects both deuterium and spin-state chemistry, and in this work our main interest is on the effect on deuterated ammonia. We applied the new models to the starless core H-MM1, where several deuterated forms of ammonia have been observed. Our investigation slightly favors the proton hop mechanism over full scrambling because the ammonia D/H ratios are better fit by the former model, although neither model can reproduce the observed NH2D ortho-to-para ratio of 3 (the models predict a value of similar to 2). Extending the proton hop scenario to hydrogen atom abstraction reactions yields a good agreement for the spin-state abundance ratios, but greatly overestimates the deuterium fractions of ammonia. However, one can find a reasonably good agreement with the observations with this model by increasing the cosmic-ray ionization rate over the commonly adopted value of similar to 10(-17) s(-1). We also find that the deuterium fractions of several other species, such as H2CO, H2O, and CH3, are sensitive to the adopted proton-donation reaction mechanism. Whether the full scrambling or proton hop mechanism dominates may be dependent on the reacting system, and new laboratory and theoretical studies for various reacting systems are needed to constrain chemical models.
Subject: astrochemistry
ISM: abundances
ISM: clouds
ISM: molecules
radiative transfer
115 Astronomy, Space science
Peer reviewed: Yes
Rights: cc_by
Usage restriction: openAccess
Self-archived version: publishedVersion

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