The Hydrophobicity of Lignocellulosic Fiber Network Can Be Enhanced with Suberin Fatty Acids

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Korpinen , R I , Kilpeläinen , P , Sarjala , T , Nurmi , M , Saloranta , P , Holmbom , T , Koivula , H , Mikkonen , K S , Willför , S & Saranpää , P T 2019 , ' The Hydrophobicity of Lignocellulosic Fiber Network Can Be Enhanced with Suberin Fatty Acids ' , Molecules , vol. 24 , no. 23 , 4391 . https://doi.org/10.3390/molecules24234391

Title: The Hydrophobicity of Lignocellulosic Fiber Network Can Be Enhanced with Suberin Fatty Acids
Author: Korpinen, Risto I.; Kilpeläinen, Petri; Sarjala, Tytti; Nurmi, Maristiina; Saloranta, Pauliina; Holmbom, Thomas; Koivula, Hanna; Mikkonen, Kirsi S.; Willför, Stefan; Saranpää, Pekka T.
Contributor organization: Department of Food and Nutrition
Food Sciences
Helsinki Institute of Sustainability Science (HELSUS)
Food Materials Science Research Group
Date: 2019
Language: eng
Number of pages: 14
Belongs to series: Molecules
ISSN: 1420-3049
DOI: https://doi.org/10.3390/molecules24234391
URI: http://hdl.handle.net/10138/310930
Abstract: Suberin fatty acids were extracted from outer bark of Silver birch (Betula pendula Roth.) using an isopropanolic sodium hydroxide solution. Laboratory sheets composed of lignocellulosic fiber networks were prepared from unbleached and unrefined softwood kraft pulp and further impregnated with suberin fatty acid monomers and cured with maleic anhydride in ethanol solution. The treatment resulted in hydrophobic surfaces, in which the contact angles remained over 120 degrees during the entire measurement. The fiber network also retained its water vapor permeability and enhanced fiber–fiber bonding resulted in improved tensile strength of the sheets. Scanning electron microscopy (SEM) images revealed that the curing agent, together with suberin fatty acids, was evenly distributed on the fiber surfaces and smoothing occurred over the wrinkled microfibrillar structure. High concentrations of the curing agent resulted in globular structures containing betulinol derivates as revealed with time-of-flight secondary ion mass spectrometry (ToF-SIMS). Also, the larger amount of suberin fatty acid monomers slightly impaired the optical properties of sheets.
Subject: 416 Food Science
116 Chemical sciences
Peer reviewed: Yes
Rights: cc_by
Usage restriction: openAccess
Self-archived version: publishedVersion


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