The Hydrophobicity of Lignocellulosic Fiber Network Can Be Enhanced with Suberin Fatty Acids

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http://hdl.handle.net/10138/310930

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Korpinen , R I , Kilpeläinen , P , Sarjala , T , Nurmi , M , Saloranta , P , Holmbom , T , Koivula , H , Mikkonen , K S , Willför , S & Saranpää , P T 2019 , ' The Hydrophobicity of Lignocellulosic Fiber Network Can Be Enhanced with Suberin Fatty Acids ' , Molecules , vol. 24 , no. 23 , 4391 . https://doi.org/10.3390/molecules24234391

Titel: The Hydrophobicity of Lignocellulosic Fiber Network Can Be Enhanced with Suberin Fatty Acids
Författare: Korpinen, Risto I.; Kilpeläinen, Petri; Sarjala, Tytti; Nurmi, Maristiina; Saloranta, Pauliina; Holmbom, Thomas; Koivula, Hanna; Mikkonen, Kirsi S.; Willför, Stefan; Saranpää, Pekka T.
Medarbetare: University of Helsinki, Department of Food and Nutrition
University of Helsinki, Department of Food and Nutrition
Datum: 2019
Språk: eng
Sidantal: 14
Tillhör serie: Molecules
ISSN: 1420-3049
Permanenta länken (URI): http://hdl.handle.net/10138/310930
Abstrakt: Suberin fatty acids were extracted from outer bark of Silver birch (Betula pendula Roth.) using an isopropanolic sodium hydroxide solution. Laboratory sheets composed of lignocellulosic fiber networks were prepared from unbleached and unrefined softwood kraft pulp and further impregnated with suberin fatty acid monomers and cured with maleic anhydride in ethanol solution. The treatment resulted in hydrophobic surfaces, in which the contact angles remained over 120 degrees during the entire measurement. The fiber network also retained its water vapor permeability and enhanced fiber–fiber bonding resulted in improved tensile strength of the sheets. Scanning electron microscopy (SEM) images revealed that the curing agent, together with suberin fatty acids, was evenly distributed on the fiber surfaces and smoothing occurred over the wrinkled microfibrillar structure. High concentrations of the curing agent resulted in globular structures containing betulinol derivates as revealed with time-of-flight secondary ion mass spectrometry (ToF-SIMS). Also, the larger amount of suberin fatty acid monomers slightly impaired the optical properties of sheets.
Subject: 416 Food Science
116 Chemical sciences
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