Photoacoustic spectroscopy of 14CH4 using a mid-infrared optical parametric oscillator

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http://urn.fi/URN:NBN:fi:hulib-202006233413
Titel: Photoacoustic spectroscopy of 14CH4 using a mid-infrared optical parametric oscillator
Författare: Larnimaa, Santeri
Medarbetare: Helsingin yliopisto, Matemaattis-luonnontieteellinen tiedekunta
University of Helsinki, Faculty of Science
Helsingfors universitet, Matematisk-naturvetenskapliga fakulteten
Utgivare: Helsingin yliopisto
Datum: 2020
Språk: eng
Permanenta länken (URI): http://urn.fi/URN:NBN:fi:hulib-202006233413
http://hdl.handle.net/10138/316932
Nivå: pro gradu-avhandlingar
Utbildningsprogram: Kemian ja molekyylitieteiden maisteriohjelma
Master's Programme in Chemistry and Molecular Sciences
Magisterprogrammet i kemi och molekylära vetenskaper
Studieinriktning: ei opintosuuntaa
no specialization
ingen studieinriktning
Ämne: none
Abstrakt: Radiomethane (14CH4) is a radioactive isotopologue of methane known to be emitted from nuclear facilities. As methane is a potent greenhouse gas and measuring the concentration of carbon-14 in a methane sample gives information about the origin of the sample, it is important to be able monitor 14CH4. The state-of-the-art method for radiomethane measurements is accelerator mass spectrometry, but optical methods have also been proposed due their affordability and suitability for field measurements. Radiomethane has already been measured with optical methods, but usually indirectly by first combusting it to carbon dioxide – direct measurement of radiomethane with optical methods would require spectroscopic information, and the first absorption spectrum of radiomethane was measured only in the year 2019. In this thesis, the exploration of the CH-stretching vibrational band ν3 of 14CH4 is continued: Total of 43 lines with 17 new lines have been measured and assigned with improved accuracy. Furthermore, the widths of the lines have been studied in detail for the first time and a simple model to estimate the 14CH4 line positions to aid possible future research on radiomethane is presented. The measurements were conducted with photoacoustic spectroscopy using frequency modulation techniques and a mid-infrared continuous-wave optical parametric oscillator (OPO) as a light source. The OPO frequency was referenced to a wavelength meter and the frequency scanning (measuring over an absorption line) was executed with a proportional–integral–derivative controller in LabVIEW. The novel results presented in this thesis are useful for possible future applications in quantitative analysis of radiomethane, and the results are also relevant for fundamental research as radiomethane is the last naturally occurring isotopologue of methane that has not yet been extensively studied with optical methods.
Subject: Radiomethane
methane
carbon-14
mid-infrared
vibrational band
optical methods
photoacoustic spectroscopy
frequency modulation
optical parametric oscillator
OPO
linewidth


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