Synthesis, Structures, and Electronic Properties of O- and S-Heterocyclic Carbene Complexes of Iridium, Copper, Silver, and Gold

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dc.contributor.author Joost, Maximilian
dc.contributor.author Nieger, Martin
dc.contributor.author Lutz, Martin
dc.contributor.author Ehlers, Andreas W.
dc.contributor.author Slootweg, Jacob Christiaan (Chris)
dc.contributor.author Lammertsma, Koop
dc.date.accessioned 2020-06-26T09:11:01Z
dc.date.available 2020-06-26T09:11:01Z
dc.date.issued 2020-05-26
dc.identifier.citation Joost , M , Nieger , M , Lutz , M , Ehlers , A W , Slootweg , J C C & Lammertsma , K 2020 , ' Synthesis, Structures, and Electronic Properties of O- and S-Heterocyclic Carbene Complexes of Iridium, Copper, Silver, and Gold ' , Organometallics , vol. 39 , no. 10 , pp. 1762-1771 . https://doi.org/10.1021/acs.organomet.0c00066
dc.identifier.other PURE: 139611185
dc.identifier.other PURE UUID: d8dcbdc2-aac4-45b9-a1b8-55ba8ca32852
dc.identifier.other WOS: 000537685700013
dc.identifier.other ORCID: /0000-0003-1677-0109/work/76330085
dc.identifier.uri http://hdl.handle.net/10138/316994
dc.description.abstract O- and S-heterocyclic carbenes (OHCs, SHCs) are shown experimentally and computationally to be stronger pi acceptors than NHCs and lack, of course, substituents at the heteroatoms. These different electronic and steric characteristics make OHCs and SHCs interesting ligands for coordination chemistry. Convenient synthetic routes are presented to access their iridium(I), iridium(III), and coinage-metal(I) (Cu, Ag, Au) complexes in good yields by means of dissociation of olefins, deprotonation of precursor salts, and transmetalation from a silver carbene complex Molecular structures and detailed bonding analyses of these complexes are presented. en
dc.format.extent 10
dc.language.iso eng
dc.relation.ispartof Organometallics
dc.rights cc_by
dc.rights.uri info:eu-repo/semantics/openAccess
dc.subject PI-ACCEPTOR PROPERTIES
dc.subject NMR CHEMICAL-SHIFTS
dc.subject X-RAY STRUCTURES
dc.subject DIOXYCARBENE COMPLEXES
dc.subject NUCLEOPHILIC CARBENES
dc.subject CRYSTAL-STRUCTURE
dc.subject METAL-CARBONYLS
dc.subject LIGANDS
dc.subject IRON
dc.subject MANGANESE
dc.subject 116 Chemical sciences
dc.title Synthesis, Structures, and Electronic Properties of O- and S-Heterocyclic Carbene Complexes of Iridium, Copper, Silver, and Gold en
dc.type Article
dc.contributor.organization Department of Chemistry
dc.description.reviewstatus Peer reviewed
dc.relation.doi https://doi.org/10.1021/acs.organomet.0c00066
dc.relation.issn 0276-7333
dc.rights.accesslevel openAccess
dc.type.version publishedVersion

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