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Catalytic Dehydrogenation of Amine-Boranes using Geminal Phosphino-Boranes

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dc.contributor.author Boom, Devin H. A.
dc.contributor.author de Boed, Ewoud J. J.
dc.contributor.author Nicolas, Emmanuel
dc.contributor.author Nieger, Martin
dc.contributor.author Ehlers, Andreas W.
dc.contributor.author Jupp, Andrew R.
dc.contributor.author Slootweg, J. Chris
dc.date.accessioned 2020-08-18T09:41:01Z
dc.date.available 2020-08-18T09:41:01Z
dc.date.issued 2020-07-15
dc.identifier.citation Boom , D H A , de Boed , E J J , Nicolas , E , Nieger , M , Ehlers , A W , Jupp , A R & Slootweg , J C 2020 , ' Catalytic Dehydrogenation of Amine-Boranes using Geminal Phosphino-Boranes ' , Zeitschrift für anorganische und allgemeine Chemie , vol. 646 , no. 13 , pp. 586-592 . https://doi.org/10.1002/zaac.201900313
dc.identifier.other PURE: 132592554
dc.identifier.other PURE UUID: aa9b90f6-4d83-453f-b769-8b804505330c
dc.identifier.other RIS: urn:E165E661E3707AFFEA7EFC4F8855D4A1
dc.identifier.other WOS: 000510457300001
dc.identifier.other ORCID: /0000-0003-1677-0109/work/79178370
dc.identifier.uri http://hdl.handle.net/10138/318384
dc.description.abstract The reaction of the intramolecular frustrated Lewis pair (FLP) tBu2PCH2BPh2 with the amine-boranes NH3·BH3 and Me2NH·BH3 leads to the formation of the corresponding FLP-H2 adducts as well as novel five-membered heterocycles that result from capturing the in situ formed amino-borane by a second equivalent of FLP. The sterically more demanding tBu2PCH2BMes2 does not form such a five-membered heterocycle when reacted with Me2NH·BH3 and its H2 adduct liberates dihydrogen at elevated temperatures, promoting the metal-free catalytic dehydrogenation of amine-boranes. en
dc.format.extent 7
dc.language.iso eng
dc.relation.ispartof Zeitschrift für anorganische und allgemeine Chemie
dc.rights cc_by_nc_nd
dc.rights.uri info:eu-repo/semantics/openAccess
dc.subject 3RD-ROW ATOMS
dc.subject AMMONIA-BORANE
dc.subject Amine-boranes
dc.subject BASIS-SETS
dc.subject DIMESITYLBORYL COMPOUNDS
dc.subject Dehydrogenation
dc.subject Density functional calculations
dc.subject FREE HYDROGEN-TRANSFER
dc.subject FRUSTRATED LEWIS PAIR
dc.subject Frustrated Lewis pairs
dc.subject GAUSSIAN-TYPE BASIS
dc.subject MOLECULAR-ORBITAL METHODS
dc.subject Main-group catalysis
dc.subject REACTIVITY
dc.subject 116 Chemical sciences
dc.title Catalytic Dehydrogenation of Amine-Boranes using Geminal Phosphino-Boranes en
dc.type Article
dc.contributor.organization Department of Chemistry
dc.description.reviewstatus Peer reviewed
dc.relation.doi https://doi.org/10.1002/zaac.201900313
dc.relation.issn 0044-2313
dc.rights.accesslevel openAccess
dc.type.version publishedVersion

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