Dual H-bond activation of NHC-Au(I)-Cl complexes with amide functionalized side-arms assisted by H-bond donor substrates or acid additives

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dc.contributor.author Seppänen, Otto
dc.contributor.author Aikonen, Santeri Alfred Arttu
dc.contributor.author Muuronen, Mikko
dc.contributor.author Alamillo-Ferrer, Carla
dc.contributor.author Burés, Jordi
dc.contributor.author Helaja, Juho
dc.date.accessioned 2020-11-30T14:56:01Z
dc.date.available 2020-11-30T14:56:01Z
dc.date.issued 2020-11-03
dc.identifier.citation Seppänen , O , Aikonen , S A A , Muuronen , M , Alamillo-Ferrer , C , Burés , J & Helaja , J 2020 , ' Dual H-bond activation of NHC-Au(I)-Cl complexes with amide functionalized side-arms assisted by H-bond donor substrates or acid additives ' , Chemical Communications , vol. 56 , no. 93 , pp. 14697–14700 . https://doi.org/10.1039/D0CC05999D
dc.identifier.other PURE: 150385690
dc.identifier.other PURE UUID: 3821bdca-3c01-458e-ad98-efbb699f6e39
dc.identifier.other ORCID: /0000-0003-2675-7290/work/84704229
dc.identifier.other ORCID: /0000-0002-5207-3493/work/85118211
dc.identifier.other WOS: 000592062700029
dc.identifier.uri http://hdl.handle.net/10138/322146
dc.description.abstract Novel approach with amide-tethered H-bond donor NHC ligands enabled Au(I)-catalysis via H-bonding. The plain NHC-Au(I)-Cl complex catalysed conversions of terminal N-propynamides to oxazolines, and enyne cycloisomerization with an acid additive, in DCM at RT. DFT calculations enlightened the function of the side-arm in the activation. fi
dc.description.abstract Novel approach with amide-tethered H-bond donor NHC ligandsenabled Au(I)-catalysisviaH-bonding. The plain NHC–Au(I)–Clcomplex catalysed conversions of terminalN-propynamides tooxazolines, and enyne cycloisomerization with an acid additive, inDCM at RT. DFT calculations enlightened the function of the side-arm in the activation. en
dc.format.extent 4
dc.language.iso eng
dc.relation.ispartof Chemical Communications
dc.rights cc_by
dc.rights.uri info:eu-repo/semantics/openAccess
dc.subject 116 Chemical sciences
dc.title Dual H-bond activation of NHC-Au(I)-Cl complexes with amide functionalized side-arms assisted by H-bond donor substrates or acid additives en
dc.type Article
dc.contributor.organization Department of Chemistry
dc.contributor.organization Juho Pekka Helaja / Principal Investigator
dc.contributor.organization Helsinki Institute of Sustainability Science (HELSUS)
dc.description.reviewstatus Peer reviewed
dc.relation.doi https://doi.org/10.1039/D0CC05999D
dc.relation.issn 1359-7345
dc.rights.accesslevel openAccess
dc.type.version publishedVersion

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