Small Variations, Big Impact : Structural Diversity of the Complexes of a Phosphane-Decorated Benzenedithiol with Group-11 Metals

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dc.contributor.author Schlindwein, Simon H.
dc.contributor.author Nieger, Martin
dc.contributor.author Gudat, Dietrich
dc.date.accessioned 2021-03-16T10:37:01Z
dc.date.available 2021-03-16T10:37:01Z
dc.date.issued 2021-02-25
dc.identifier.citation Schlindwein , S H , Nieger , M & Gudat , D 2021 , ' Small Variations, Big Impact : Structural Diversity of the Complexes of a Phosphane-Decorated Benzenedithiol with Group-11 Metals ' , European Journal of Inorganic Chemistry , vol. 2021 , no. 8 , pp. 748-755 . https://doi.org/10.1002/ejic.202001026
dc.identifier.other PURE: 161265241
dc.identifier.other PURE UUID: c5ec0d74-78e6-4134-b566-2645f8a3c46d
dc.identifier.other WOS: 000616772000001
dc.identifier.other ORCID: /0000-0003-1677-0109/work/90905447
dc.identifier.uri http://hdl.handle.net/10138/328061
dc.description.abstract Reaction of a phosphane-decorated benzenedithiol (pbdtH(2)) with coinage metal salts furnished polynuclear complexes [M-2(pbdtH)(2)] (M=Au-I) or [cat][M-5(pbdt)(3)] (cat=unipositive cation, M=Ag-I, Cu-I), which were characterized by analytical and spectroscopic techniques and single-crystal X-ray diffraction studies. Furthermore, a double salt with an anion [Ag-5(pbdt)(3)(PPh3)](-) that proved unstable in solution was characterized crystallographically. The spectroscopic and crystallographic data revealed that the Cu(I) and Ag(I) complexes exhibit, despite their like stoichiometric composition, isomeric molecular structures. The observed disparities were reproduced by DFT studies. The dinuclear Au(I) complex was found to undergo air-oxidation to furnish a mixed-valent complex [(Au-III)(2)(Au-I)(2)(pbdt)(4)]. The copper(I) - but not the isomeric silver(I) complexes - showed luminescence in the solid state. en
dc.format.extent 8
dc.language.iso eng
dc.relation.ispartof European Journal of Inorganic Chemistry
dc.rights cc_by
dc.rights.uri info:eu-repo/semantics/openAccess
dc.subject Sulfur ligands
dc.subject Phosphane ligands
dc.subject Coinage metals
dc.subject Bridging ligands
dc.subject Aggregation
dc.subject COORDINATION CHEMISTRY
dc.subject PHOSPHORUS
dc.subject LIGANDS
dc.subject ENANTIOSELECTIVITY
dc.subject DESIGN
dc.subject AU
dc.subject 116 Chemical sciences
dc.title Small Variations, Big Impact : Structural Diversity of the Complexes of a Phosphane-Decorated Benzenedithiol with Group-11 Metals en
dc.type Article
dc.contributor.organization Department of Chemistry
dc.description.reviewstatus Peer reviewed
dc.relation.doi https://doi.org/10.1002/ejic.202001026
dc.relation.issn 1434-1948
dc.rights.accesslevel openAccess
dc.type.version publishedVersion

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