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Separation of isomeric cereal-derived arabinoxylan-oligosaccharides by collision induced dissociation - travelling wave ion mobility spectrometry - tandem mass spectrometry (CID-TWIMS-MS/MS)

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dc.contributor.author Juvonen, Minna
dc.contributor.author Bakx, Edwin
dc.contributor.author Schols, Henk
dc.contributor.author Tenkanen, Maija
dc.date.accessioned 2021-09-23T13:17:01Z
dc.date.available 2021-09-23T13:17:01Z
dc.date.issued 2022-01-01
dc.identifier.citation Juvonen , M , Bakx , E , Schols , H & Tenkanen , M 2022 , ' Separation of isomeric cereal-derived arabinoxylan-oligosaccharides by collision induced dissociation - travelling wave ion mobility spectrometry - tandem mass spectrometry (CID-TWIMS-MS/MS) ' , Food Chemistry , vol. 366 , 130544 . https://doi.org/10.1016/j.foodchem.2021.130544
dc.identifier.other PURE: 165777686
dc.identifier.other PURE UUID: 72bb2a04-d456-468c-bb68-21885c12045c
dc.identifier.other WOS: 000694719800001
dc.identifier.other ORCID: /0000-0003-2883-2717/work/100452700
dc.identifier.uri http://hdl.handle.net/10138/334570
dc.description.abstract The potential of travelling wave ion mobility spectroscopy in combination with collision induced dissociation tandem mass spectrometry (CID-TWIMS-MS/MS) to separate cereal-derived isomeric arabinoxylanoligosaccharides (A)XOS was investigated. Three trisaccharide, four tetrasaccharide, and four pentasaccharide (A)XOS isomers were analyzed by positive and negative ionization TWIMS-MS and CID-TWIMS-MS/MS. The triand pentasaccharide isomers were distinguishable by the ATDs of the precursor ions. The CID-TWIMS-MS/MS could separate most of the isomeric fragment ions produced from tetra- and pentasaccharide (A)XOS. Finally, the base peak mobility spectrum is introduced as a practical tool for (A)XOS fingerprinting. en
dc.format.extent 9
dc.language.iso eng
dc.relation.ispartof Food Chemistry
dc.rights cc_by
dc.rights.uri info:eu-repo/semantics/openAccess
dc.subject 416 Food Science
dc.subject 116 Chemical sciences
dc.subject Arabinoxylan
dc.subject Oligosaccharides
dc.subject Ion mobility spectrometry
dc.subject Tandem mass spectrometry
dc.subject STRUCTURAL-ANALYSIS
dc.subject CROSS-SECTIONS
dc.subject PART 1
dc.subject IDENTIFICATION
dc.subject DISACCHARIDES
dc.subject LINKAGE
dc.subject DIFFERENTIATION
dc.subject FRAGMENTATION
dc.subject SPECTRA
dc.subject ANOMERS
dc.title Separation of isomeric cereal-derived arabinoxylan-oligosaccharides by collision induced dissociation - travelling wave ion mobility spectrometry - tandem mass spectrometry (CID-TWIMS-MS/MS) en
dc.type Article
dc.contributor.organization Department of Food and Nutrition
dc.contributor.organization Carbohydrate Chemistry and Enzymology
dc.description.reviewstatus Peer reviewed
dc.relation.doi https://doi.org/10.1016/j.foodchem.2021.130544
dc.relation.issn 0308-8146
dc.rights.accesslevel openAccess
dc.type.version publishedVersion

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