Synthesis and Theoretical Studies of Aromatic Azaborines

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Hirva, P.; Turhanen, P.; Timonen, J.M. Synthesis and Theoretical Studies of Aromatic Azaborines. Organics 2022, 3, 196-209.

Title: Synthesis and Theoretical Studies of Aromatic Azaborines
Author: Hirva, Pipsa; Turhanen, Petri; Timonen, Juri M.
Publisher: Multidisciplinary Digital Publishing Institute
Date: 2022-07-11
Abstract: Organoboron compounds are well known for their use as synthetic building blocks in several significant reactions, e.g., palladium-catalyzed Suzuki-Miyaura cross-coupling. As an element, boron is fascinating; as part of a molecule it structurally resembles a three-valent atom, but if there is a lone pair of electrons nearby, the boron atom’s empty p-orbital may capture the lone pair and form a covalent bond. This is the main aspect that is challenging chemistry during the synthesis of boron containing molecules and may lead into unexpected reactions and products. To study this, we synthesized and studied novel aromatic azaborines for better understanding of their structures and reactions. Here, we report a one-pot method for the synthesis of substituted aromatic azaborines and computational studies of their structure to explain their observed chemical properties.

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