Browsing Asiantuntijatarkastetut julkaisut - Refereed publications by Title

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  • Sebastian, Mathew; Kompalli, Sobhan Kumar; Kumar, Vasudevan Anil; Jose, Sandhya; Babu, S. Suresh; Pandithurai, Govindan; Singh, Sachchidanand; Hooda, Rakesh K.; Soni, Vijay K.; Pierce, Jeffrey R.; Vakkari, Ville; Asmi, Eija; Westervelt, Daniel M.; Hyvärinen, Antti-Pekka; Kanawade, Vijay P. (Copernicus Publ., 2022)
    Atmospheric chemistry and physics
    Atmospheric new particle formation (NPF) is a crucial process driving aerosol number concentrations in the atmosphere; it can significantly impact the evolution of atmospheric aerosol and cloud processes. This study analyses at least 1 year of asynchronous particle number size distributions from six different locations in India. We also analyze the frequency of NPF and its contribution to cloud condensation nuclei (CCN) concentrations. We found that the NPF frequency has a considerable seasonal variability. At the measurement sites analyzed in this study, NPF frequently occurs in March–May (pre-monsoon, about 21 % of the days) and is the least common in October–November (post-monsoon, about 7 % of the days). Considering the NPF events in all locations, the particle formation rate (JSDS) varied by more than 2 orders of magnitude (0.001–0.6 cm−3s−1) and the growth rate between the smallest detectable size and 25 nm (GRSDS-25 nm) by about 3 orders of magnitude (0.2–17.2 nm h−1). We found that JSDS was higher by nearly 1 order of magnitude during NPF events in urban areas than mountain sites. GRSDS did not show a systematic difference. Our results showed that NPF events could significantly modulate the shape of particle number size distributions and CCN concentrations in India. The contribution of a given NPF event to CCN concentrations was the highest in urban locations (4.3 × 103cm−3 per event and 1.2 × 103cm−3 per event for 50 and 100 nm, respectively) as compared to mountain background sites (2.7 × 103cm−3 per event and 1.0 × 103cm−3 per event, respectively). We emphasize that the physical and chemical pathways responsible for NPF and factors that control its contribution to CCN production require in situ field observations using recent advances in aerosol and its precursor gaseous measurement techniques.
  • Kuula, Joel; Timonen, Hilkka; Niemi, Jarkko V.; Manninen, Hanna E.; Rönkkö, Topi; Hussein, Tareq; Fung, Pak Lun; Tarkoma, Sasu; Laakso, Mikko; Saukko, Erkka; Ovaska, Aino; Kulmala, Markku; Karppinen, Ari; Johansson, Lasse; Petäjä, Tuukka (Copernicus GmbH, 2022)
    Atmospheric Chemistry and Physics
    As evidence of adverse health effects due to air pollution continues to increase, the World Health Organization (WHO) recently published its latest edition of the global air quality guidelines (World Health Organization, 2021). Although not legally binding, the guidelines aim to provide a framework in which policymakers can combat air pollution by formulating evidence-based air quality management strategies. In the light of this, the European Union has stated its intent to revise the current ambient air quality directive (2008/50/EC) to more closely resemble the newly published WHO guidelines (European Commission, 2020). This article provides an informed opinion on selected features of the air quality directive that we believe would benefit from a reassessment. The selected features include discussion about (1) air quality sensors as a part of a hierarchical observation network, (2) the number of minimum sampling points and their siting criteria, and (3) new target air pollution parameters for future consideration.
  • Luo, Yuanyuan; Garmash, Olga; Li, Haiyan; Graeffe, Frans; Praplan, Arnaud P.; Liikanen, Anssi; Zhang, Yanjun; Meder, Melissa; Peräkylä, Otso; Pẽnuelas, Josep; Yáñez-Serrano, Ana María; Ehn, Mikael (Copernicus Publ., 2022)
    Atmospheric chemistry and physics
    Diterpenes (C20H32) are biogenically emitted volatile compounds that only recently have been observed in ambient air. They are expected to be highly reactive, and their oxidation is likely to form condensable vapors. However, until now, no studies have investigated gas-phase diterpene oxidation. In this paper, we explored the ozonolysis of a diterpene, ent-kaurene, in a simulation chamber. Using state-of-the-art mass spectrometry, we characterized diterpene oxidation products for the first time, and we identified several products with varying oxidation levels, including highly oxygenated organic molecules (HOM), monomers, and dimers. The most abundant monomers measured using a nitrate chemical ionization mass spectrometer were C19H28O8 and C20H30O5, and the most abundant dimers were C38H60O6 and C39H62O6. The exact molar yield of HOM from kaurene ozonolysis was hard to quantify due to uncertainties in both the kaurene and HOM concentrations, but our best estimate was a few percent, which is similar to values reported earlier for many monoterpenes. We also monitored the decrease in the gas-phase oxidation products in response to an increased condensation sink in the chamber to deduce their affinity to condense. The oxygen content was a critical parameter affecting the volatility of products, with four to five O atoms needed for the main monomeric species to condense onto 80 nm particles. Finally, we report on the observed fragmentation and clustering patterns of kaurene in a Vocus proton-transferreaction time-of-flight mass spectrometer. Our findings highlight similarities and differences between diterpenes and smaller terpenes during their atmospheric oxidation, but more studies on different diterpenes are needed for a broader view of their role in atmospheric chemistry.
  • Lacagnina, Carlo; Doblas-Reyes, Francisco; Larnicol, Gilles; Buontempo, Carlo; Obregón, André; Costa-Surós, Montserrat; San-Martín, Daniel; Bretonnière, Pierre-Antoine; Polade, Suraj D.; Romanova, Vanya; Putero, Davide; Serva, Federico; Llabrés-Brustenga, Alba; Pérez, Antonio; Cavaliere, Davide; Membrive, Olivier; Steger, Christian; Pérez-Zanón, Núria; Cristofanelli, Paolo; Madonna, Fabio; Rosoldi, Marco; Riihelä, Aku; Díez, Markel García (Ubiquity Press, Ltd., 2022)
    Data Science Journal
    Data from a variety of research programmes are increasingly used by policy makers, researchers, and private sectors to make data-driven decisions related to climate change and variability. Climate services are emerging as the link to narrow the gap between climate science and downstream users. The Global Framework for Climate Services (GFCS) of the World Meteorological Organization (WMO) offers an umbrella for the development of climate services and has identified the quality assessment, along with its use in user guidance, as a key aspect of the service provision. This offers an extra stimulus for discussing what type of quality information to focus on and how to present it to downstream users. Quality has become an important keyword for those working on data in both the private and public sectors and significant resources are now devoted to quality management of processes and products. Quality management guarantees reliability and usability of the product served, it is a key element to build trust between consumers and suppliers. Untrustworthy data could lead to a negative economic impact at best and a safety hazard at worst. In a progressive commitment to establish this relation of trust, as well as providing sufficient guidance for users, the Copernicus Climate Change Service (C3S) has made significant investments in the development of an Evaluation and Quality Control (EQC) function. This function offers a homogeneous user-driven service for the quality of the C3S Climate Data Store (CDS). Here we focus on the EQC component targeting the assessment of the CDS datasets, which include satellite and in-situ observations, reanalysis, climate projections, and seasonal forecasts. The EQC function is characterised by a two-tier review system designed to guarantee the quality of the dataset information. While the need of assessing the quality of climate data is well recognised, the methodologies, the metrics, the evaluation framework, and how to present all this information to the users have never been developed before in an operational service, encompassing all the main climate dataset categories. Building the underlying technical solutions poses unprecedented challenges and makes the C3S EQC approach unique. This paper describes the development and the implementation of the operational EQC function providing an overarching quality management service for the whole CDS data.
  • Kruglyakov, Mikhail; Kuvshinov, Alexey; Marshalko, Elena (American Geophysical Union, 2022)
    Space weather: the international journal of research and applications
    We present a methodology that allows researchers to simulate in real time the spatiotemporal dynamics of the ground electric field (GEF) in a given 3-D conductivity model of the Earth based on continuously augmented data on the spatiotemporal evolution of the inducing source. The formalism relies on the factorization of the source by spatial modes (SM) and time series of respective expansion coefficients and exploits precomputed GEF kernels generated by corresponding SM. To validate the formalism, we invoke a high-resolution 3-D conductivity model of Fennoscandia and consider a realistic source built using the Spherical Elementary Current Systems (SECS) method as applied to magnetic field data from the International Monitor for Auroral Geomagnetic Effect network of observations. The factorization of the SECS-recovered source is then performed using the principal component analysis. Eventually, we show that the GEF computation at a given time instant on a 512 × 512 grid requires less than 0.025 s provided that GEF kernels due to pre-selected SM are computed in advance. Taking the 7–8 September 2017 geomagnetic storm as a space weather event, we show that real-time high-resolution 3-D modeling of the GEF is feasible. This opens a practical opportunity for GEF (and eventually geomagnetically induced currents) nowcasting and forecasting.
  • Ahola, Jaakko; Raatikainen, Tomi; Alper, Muzaffer Ege; Keskinen, Jukka-Pekka; Kokkola, Harri; Kukkurainen, Antti; Lipponen, Antti; Liu, Jia; Nordling, Kalle; Partanen, Antti-Ilari; Romakkaniemi, Sami; Räisänen, Petri; Tonttila, Juha; Korhonen, Hannele (Copernicus Publ., 2022)
    Atmospheric chemistry and physics
    The number of cloud droplets formed at the cloud base depends on both the properties of aerosol particles and the updraft velocity of an air parcel at the cloud base. As the spatial scale of updrafts is too small to be resolved in global atmospheric models, the updraft velocity is commonly parameterised based on the available turbulent kinetic energy. Here we present alternative methods through parameterising updraft velocity based on high-resolution large-eddy simulation (LES) runs in the case of marine stratocumulus clouds. First we use our simulations to assess the accuracy of a simple linear parameterisation where the updraft velocity depends only on cloud top radiative cooling. In addition, we present two different machine learning methods (Gaussian rocess emulation and random forest) that account for different boundary layer conditions and cloud properties. We conclude that both machine learning parameterisations reproduce the LES-based updraft velocities at about the same accuracy, while the simple approach employing radiative cooling only produces on average lower coefficient of determination and higher root mean square error values. Finally, we apply these machine learning methods to find the key parameters affecting cloud base updraft velocities.
  • Raatikainen, Tomi; Prank, Marje; Ahola, Jaakko; Kokkola, Harri; Tonttila, Juha; Romakkaniemi, Sami (Copernicus Publ., 2022)
    Atmospheric chemistry and physics
    Shallow marine mixed-phase clouds are important for the Earth’s radiative balance, but modelling their formation and dynamics is challenging. These clouds depend on boundary layer turbulence and cloud top radiative cooling, which is related to the cloud phase. The fraction of frozen droplets depends on the availability of suitable ice-nucleating particles (INPs), which initiate droplet freezing. While mineral dust is the dominating INP type in most regions, high-latitude boundary layer clouds can be dependent on local marine INP emissions, which are often related to biogenic sources including phytoplankton. Here we use high resolution large eddy simulations to examine the potential effects of marine emissions on boundary layer INP concentrations and their effects on clouds. Surface emissions have a direct effect on INP concentration in a typical well-mixed boundary layer whereas a steep inversion can block the import of background INPs from the free troposphere. The importance of the marine source depends on the background INP concentration, so that marine INP emissions become more important with lower background INP concentrations. For the INP budget it is also important to account for INP recycling. Finally, with the high-resolution model we show how ice nucleation hotspots and high INP concentrations are focused on updraught regions. Our results show that marine INP emissions contribute directly to the boundary layer INP budget and therefore have an influence on mixed-phase clouds.