TY  -  
T1  - Intramolecular structure and energetics in supercooled water down to 255 K 
SN  -  /  
UR  - http://hdl.handle.net/10138/224394 
T3  -  
A1  - Lehmkuehler, Felix; Forov, Yury; Buening, Thomas; Sahle, Christoph J.; Steinke, Ingo; Julius, Karin; Buslaps, Thomas; Tolan, Metin; Hakala, Mikko; Sternemann, Christian 
A2  -  
PB  -  
Y1  - 2016 
LA  - eng 
AB  - We studied the structure and energetics of supercooled water by means of X-ray Raman and Compton scattering. Under supercooled conditions down to 255 K, the oxygen K-edge measured by X-ray Raman scattering suggests an increase of tetrahedral order similar to the conventional temperature effect observed in non-supercooled water. Compton profile differences indicate contributions beyond the theoretically predicted temperature effect and provide a deeper insight into local structural changes. These... 
VO  -  
IS  -  
SP  -  
OP  -  
KW  - HYDROGEN-BOND NETWORK; LIQUID WATER; RAMAN-SCATTERING; TETRAHYDROFURAN CLATHRATE; TEMPERATURE-DEPENDENCE; HEAT-CAPACITY; EDGE SPECTRUM; ICE; AMBIENT; 116 Chemical sciences; 114 Physical sciences 
N1  -   
PP  -  
ER  -