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T1  - Kinetics of the Methyl-Vinyl Radical + O-2 Reactions Associated with Propene Oxidation 
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UR  - http://hdl.handle.net/10138/301150 
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A1  - Joshi, Satya P.; Pekkanen, Timo T.; Timonen, Raimo S.; Lendvay, Gyorgy; Eskola, Arkke J. 
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PB  -  
Y1  - 2019 
LA  - eng 
AB  - The bimolecular rate coefficients of reactions CH3CCH2 + O-2 (1) and cis/trans-CH3CHCH + O-2 (2a/3a) have been measured using a tubular laminar flow reactor coupled with a photoionization mass spectrometer (PIMS). These reactions are relevant in the combustion of propene. Pulsed excimer laser photolysis of a ketone or a bromide precursor molecule at 193 or 248 nm wavelength was used to produce radicals of interest homogeneously along the reactor. Time-resolved experiments were performed under ps... 
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KW  - ACTIVE THERMOCHEMICAL TABLES; TEMPERATURES; OXIDATION; CHLORINE; IGNITION; OCTANE; OXYGEN; TIME; 116 Chemical sciences 
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