TY - T1 - OBO-Fused Benzo[fg]tetracene as Acceptor With Potential for Thermally Activated Delayed Fluorescence Emitters SN - / UR - http://hdl.handle.net/10138/321044 T3 - A1 - Zhang, Zhen; Kumar, Shiv; Bagnich, Sergey; Spuling, Eduard; Hundemer, Fabian; Nieger, Martin; Hassan, Zahid; Köhler, Anna; Zysman-Colman, Eli; Bräse, Stefan A2 - PB - Y1 - 2020 LA - eng AB - Six luminophores bearing an OBO-fused benzo[fg]tetracene core as an electron acceptor were designed and synthesized. The molecular structures of three molecules (PXZ-OBO, 5PXZ-OBO, 5DMAC-OBO) were determined by single crystal X-ray diffraction studies and revealed significant torsion between the donor moieties and the OBO acceptor with dihedral angles between 75.5 and 86.2 degrees. Photophysical studies demonstrate that blue and deep blue emission can be realized with photoluminescence maxima (l... VO - IS - SP - OP - KW - boron emitters; fluorescence; OLED; TADF; boron; LIGHT-EMITTING-DIODES; HIGH-EFFICIENCY; 116 Chemical sciences N1 - PP - ER -