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T1  - Small Variations, Big Impact : Structural Diversity of the Complexes of a Phosphane-Decorated Benzenedithiol with Group-11 Metals 
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UR  - http://hdl.handle.net/10138/328061 
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A1  - Schlindwein, Simon H.; Nieger, Martin; Gudat, Dietrich 
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Y1  - 2021 
LA  - eng 
AB  - Reaction of a phosphane-decorated benzenedithiol (pbdtH(2)) with coinage metal salts furnished polynuclear complexes [M-2(pbdtH)(2)] (M=Au-I) or [cat][M-5(pbdt)(3)] (cat=unipositive cation, M=Ag-I, Cu-I), which were characterized by analytical and spectroscopic techniques and single-crystal X-ray diffraction studies. Furthermore, a double salt with an anion [Ag-5(pbdt)(3)(PPh3)](-) that proved unstable in solution was characterized crystallographically. The spectroscopic and crystallographic dat... 
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KW  - Sulfur ligands; Phosphane ligands; Coinage metals; Bridging ligands; Aggregation; COORDINATION CHEMISTRY; PHOSPHORUS; LIGANDS; ENANTIOSELECTIVITY; DESIGN; AU; 116 Chemical sciences 
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