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T1  - Transition-Metal-Doped NIR-Emitting Silicon Nanocrystals 
SN  -  /  
UR  - http://hdl.handle.net/10138/209588 
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A1  - Chandra, Sourov; Masuda, Yoshitake; Shirahata, Naoto; Winnik, Francoise M. 
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PB  -  
Y1  - 2017 
LA  - eng 
AB  - Impurity-doping in nanocrystals significantly affects their electronic properties and diversifies their applications. Herein, we report the synthesis of transition metal (Mn, Ni, Co, Cu)-doped oleophilic silicon nanocrystals (SiNCs) through hydrolysis/polymerization of triethoxysilane with acidic aqueous metal salt solutions, followed by thermal disproportionation of the resulting gel into a doped-Si/SiO2 composite that, upon HF etching and hydrosilylation with 1-n-octadecene, produces free-stan... 
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KW  - doping; nanocrystals; photoluminescence; silicon; thermal disproportionation; QUANTUM DOTS; SEMICONDUCTOR NANOCRYSTALS; OPTICAL-PROPERTIES; PHOTOLUMINESCENCE; IMPURITIES; NANOPARTICLES; LUMINESCENCE; 116 Chemical sciences 
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