Determination of physical emulsion stabilization mechanisms of wood hemicelluloses via rheological and interfacial characterization

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http://hdl.handle.net/10138/224388

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Mikkonen , K S , Merger , D , Kilpeläinen , P , Murtomäki , L , Schmidt , U S & Wilhelm , M 2016 , ' Determination of physical emulsion stabilization mechanisms of wood hemicelluloses via rheological and interfacial characterization ' , Soft Matter , vol. 12 , no. 42 , pp. 8690-8700 . https://doi.org/10.1039/C6SM01557C

Title: Determination of physical emulsion stabilization mechanisms of wood hemicelluloses via rheological and interfacial characterization
Author: Mikkonen, Kirsi Susanna; Merger, Dimitri; Kilpeläinen, Petri; Murtomäki, Lasse; Schmidt, Ulrike S.; Wilhelm, Manfred
Contributor: University of Helsinki, Department of Food and Nutrition
Date: 2016
Language: eng
Number of pages: 10
Belongs to series: Soft Matter
ISSN: 1744-683X
URI: http://hdl.handle.net/10138/224388
Abstract: Materials manufacturing industries seek efficient, economic, and sustainable compounds for stabilizing dispersed systems such as emulsions. In this study, novel, abundant biobased hydrocolloids spruce galactoglucomannans (GGM) and birch glucuronoxylans (GX) were obtained from a forestry biorefining process and characterized as versatile stabilizers of rapeseed oil-in-water emulsions. For the first time, GGM and GX isolated by pressurized hot water extraction (PHWE) of spruce and birch saw meal, respectively, were studied in emulsions. The PHWE wood hemicelluloses—polysaccharides with relatively low molar mass—facilitated the formation of emulsions with small average droplet size and efficiently prevented droplet coalescence. GGM and GX lowered the surface tension of emulsions’ oil–water interface and increased the viscosity of the continuous phase. However, viscosity of the wood hemicellulose-based systems was low compared to that of commercial polymeric stabilizers. GGMstabilized emulsions with varying oil volume fractions were characterized in terms of their rheological properties, including large amplitude oscillation shear (LAOS) measurements, and compared to emulsions prepared with a classical small-molecular surfactant, Tween20. The physical emulsion stabilization mechanisms of GGM and GX are suggested as steric repulsion assisted by Pickering-type stabilization. Wood hemicelluloses have potential as highly promising future bioproducts for versatile industrial applications involving colloidal systems and soft materials.
Subject: 416 Food Science
Emulsions
Polysaccharides
Stability
Rheology
116 Chemical sciences
Carbohydrate analysis
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