A highly stable, Au/Ru heterobimetallic photoredox catalyst with a [2.2]paracyclophane backbone

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Knoll , D M , Zippel , C , Hassan , Z , Nieger , M , Weis , P , Kappes , M M & Braese , S 2019 , ' A highly stable, Au/Ru heterobimetallic photoredox catalyst with a [2.2]paracyclophane backbone ' , Dalton Transactions , vol. 48 , no. 48 , pp. 17704-17708 . https://doi.org/10.1039/c9dt04366g

Title: A highly stable, Au/Ru heterobimetallic photoredox catalyst with a [2.2]paracyclophane backbone
Author: Knoll, Daniel M.; Zippel, Christoph; Hassan, Zahid; Nieger, Martin; Weis, Patrick; Kappes, Manfred M.; Braese, Stefan
Contributor: University of Helsinki, Department of Chemistry
Date: 2019-12-28
Language: eng
Number of pages: 5
Belongs to series: Dalton Transactions
ISSN: 1477-9226
URI: http://hdl.handle.net/10138/311231
Abstract: We report the synthesis and catalytic application of a highly stable distance-defined Au/Ru heterobimetallic complex. [2.2]Paracyclophane serves as a backbone, holding the two metal centers in a spatial orientation and metal-metal fixed distance. The Au/Ru heterobimetallic complex is highly stable, easily accessible and exhibits promising catalytic activity in a visible-light mediated dual Au/Ru Meyer-Schuster rearrangement.
Subject: HETEROMETALLIC COMPLEXES
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116 Chemical sciences
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