A method for designing a novel class of gold-containing molecules

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http://hdl.handle.net/10138/316269

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Celaya , C A , Orozco-Ic , M , Dimitrova , M , Wirz , L N & Sundholm , D 2020 , ' A method for designing a novel class of gold-containing molecules ' , Chemical Communications , vol. 56 , no. 40 , pp. 5433-5436 . https://doi.org/10.1039/d0cc01227k

Title: A method for designing a novel class of gold-containing molecules
Author: Celaya, Christian A.; Orozco-Ic, Mesias; Dimitrova, Maria; Wirz, Lukas N.; Sundholm, Dage
Contributor: University of Helsinki, Department of Chemistry
University of Helsinki, Department of Chemistry
University of Helsinki, Department of Chemistry
University of Helsinki, Department of Chemistry
Date: 2020-05-18
Language: eng
Number of pages: 4
Belongs to series: Chemical Communications
ISSN: 1359-7345
URI: http://hdl.handle.net/10138/316269
Abstract: We propose a novel class of gold-containing molecules, which have been designed using conjugated carbon structures as templates. The sp-hybridized carbons of C-2 moieties are replaced with a gold atom and one of the adjacent carbons is replaced by nitrogen. Applying the procedure to hexadehydro[12]annulene yields the well-known cyclic trinuclear gold(i) carbeniate complex. Planar, tubular and cage-shaped complexes can be obtained by taking similar sp-hybridized carbon structures as the starting point.
Subject: INTERMOLECULAR GLUE
CARBON
SOLVOLUMINESCENCE
LUMINESCENCE
NANOSTRIPS
COMPLEXES
INSIGHTS
HOLLOW
116 Chemical sciences
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