A versatile Diels-Alder approach to functionalized hydroanthraquinones

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dc.contributor.author Beck, Janina
dc.contributor.author Fuhr, Olaf
dc.contributor.author Nieger, Martin
dc.contributor.author Bräse, Stefan
dc.date.accessioned 2020-12-18T07:24:01Z
dc.date.available 2020-12-18T07:24:01Z
dc.date.issued 2020-11-18
dc.identifier.citation Beck , J , Fuhr , O , Nieger , M & Bräse , S 2020 , ' A versatile Diels-Alder approach to functionalized hydroanthraquinones ' , Royal Society Open Science , vol. 7 , no. 11 , 200626 . https://doi.org/10.1098/rsos.200626
dc.identifier.other PURE: 157732885
dc.identifier.other PURE UUID: 7faf7bbd-5d44-4e46-91ec-49f975dc133a
dc.identifier.other WOS: 000595462200001
dc.identifier.other ORCID: /0000-0003-1677-0109/work/85517225
dc.identifier.other Scopus: 85097951466
dc.identifier.uri http://hdl.handle.net/10138/323375
dc.description.abstract The synthesis of highly substituted hydroanthraquinone derivatives with up to three stereogenic centres via a Diels-Alder reaction, starting from easily accessible 2-substituted naphthoquinones, is described. The [4+2]-cycloaddition is applicable for a broad range of substrates, runs under mild conditions and results in high yields. The highly regioselective outcome of the reactions is enabled by a benzoyl substituent at C2 of the dienophiles. The obtained hydroanthraquinones can be further modified and represent ideal substrates for follow-up intramolecular coupling reactions to create unique bicyclo[3.3.1] or -[3.2.2]nonane ring systems which are important natural product skeletons. en
dc.format.extent 16
dc.language.iso eng
dc.relation.ispartof Royal Society Open Science
dc.rights cc_by
dc.rights.uri info:eu-repo/semantics/openAccess
dc.subject cycloaddition
dc.subject natural product
dc.subject carbocycle
dc.subject INHIBITION
dc.subject ANNULATION
dc.subject MOLECULES
dc.subject PIGMENTS
dc.subject FUNGI
dc.subject 116 Chemical sciences
dc.title A versatile Diels-Alder approach to functionalized hydroanthraquinones en
dc.type Article
dc.contributor.organization Department of Chemistry
dc.description.reviewstatus Peer reviewed
dc.relation.doi https://doi.org/10.1098/rsos.200626
dc.relation.issn 2054-5703
dc.rights.accesslevel openAccess
dc.type.version publishedVersion

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