Aerosol formation and growth rates from chamber experiments using Kalman smoothing

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Ozon , M , Stolzenburg , D , Dada , L , Seppänen , A & Lehtinen , K E J 2021 , ' Aerosol formation and growth rates from chamber experiments using Kalman smoothing ' , Atmospheric Chemistry and Physics , vol. 21 , no. 16 , pp. 12595-12611 . https://doi.org/10.5194/acp-21-12595-2021

Title: Aerosol formation and growth rates from chamber experiments using Kalman smoothing
Author: Ozon, Matthew; Stolzenburg, Dominik; Dada, Lubna; Seppänen, Aku; Lehtinen, Kari E. J.
Contributor organization: Institute for Atmospheric and Earth System Research (INAR)
Air quality research group
Date: 2021-08-23
Language: eng
Number of pages: 17
Belongs to series: Atmospheric Chemistry and Physics
ISSN: 1680-7316
DOI: https://doi.org/10.5194/acp-21-12595-2021
URI: http://hdl.handle.net/10138/335099
Abstract: Bayesian state estimation in the form of Kalman smoothing was applied to differential mobility analyser train (DMA-train) measurements of aerosol size distribution dynamics. Four experiments were analysed in order to estimate the aerosol size distribution, formation rate, and size-dependent growth rate, as functions of time. The first analysed case was a synthetic one, generated by a detailed aerosol dynamics model and the other three chamber experiments performed at the CERN CLOUD facility. The estimated formation and growth rates were compared with other methods used earlier for the CLOUD data and with the true values for the computer-generated synthetic experiment. The agreement in the growth rates was very good for all studied cases: estimations with an earlier method fell within the uncertainty limits of the Kalman smoother results. The formation rates also matched well, within roughly a factor of 2.5 in all cases, which can be considered very good considering the fact that they were estimated from data given by two different instruments, the other being the particle size magnifier (PSM), which is known to have large uncertainties close to its detection limit. The presented fixed interval Kalman smoother (FIKS) method has clear advantages compared with earlier methods that have been applied to this kind of data. First, FIKS can reconstruct the size distribution between possible size gaps in the measurement in such a way that it is consistent with aerosol size distribution dynamics theory, and second, the method gives rise to direct and reliable estimation of size distribution and process rate uncertainties if the uncertainties in the kernel functions and numerical models are known.Bayesian state estimation in the form of Kalman smoothing was applied to differential mobility analyser train (DMA-train) measurements of aerosol size distribution dynamics. Four experiments were analysed in order to estimate the aerosol size distribution, formation rate, and size-dependent growth rate, as functions of time. The first analysed case was a synthetic one, generated by a detailed aerosol dynamics model and the other three chamber experiments performed at the CERN CLOUD facility. The estimated formation and growth rates were compared with other methods used earlier for the CLOUD data and with the true values for the computer-generated synthetic experiment. The agreement in the growth rates was very good for all studied cases: estimations with an earlier method fell within the uncertainty limits of the Kalman smoother results. The formation rates also matched well, within roughly a factor of 2.5 in all cases, which can be considered very good considering the fact that they were estimated from data given by two different instruments, the other being the particle size magnifier (PSM), which is known to have large uncertainties close to its detection limit. The presented fixed interval Kalman smoother (FIKS) method has clear advantages compared with earlier methods that have been applied to this kind of data. First, FIKS can reconstruct the size distribution between possible size gaps in the measurement in such a way that it is consistent with aerosol size distribution dynamics theory, and second, the method gives rise to direct and reliable estimation of size distribution and process rate uncertainties if the un-certainties in the kernel functions and numerical models are known.
Subject: 114 Physical sciences
Peer reviewed: Yes
Rights: cc_by
Usage restriction: openAccess
Self-archived version: publishedVersion


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